By A.W. Parkins
This e-book offers an built-in view of the organometallic chemistry of transition and non-transition components. Early chapters care for the fundamental rules, practise and constitution of organometallic compounds. next chapters speak about the reactivity of those compounds and the functions of organometallic compounds as stoichiometric reagents and catalysts. The textual content is comprehensively referenced all through and can also be a advisor to organometallic literature, expanding its usefulness to all these thinking about the examine or instructing of this more and more very important department of undergraduate chemistry.
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Extra resources for An Introduction to Organometallic Chemistry
1979). Rev. Silicon, Germanium, Tin Lead Compounds 4, 59 Moser, G. , and Rausch, M. D. (1974). Synth. React. inorg. Metal-org. Chem. 4,37 Murphy, J. and Poller, R. C. (1980). J. organomet. Chem. Library 9, 189 Negishi, E. I. (1980). Organometallics in Organic Synthesis, Vol. 1. Wiley, New York Owen, D. , and Poller, R. C. J. organomet. Chem. 255,173 Parham, W. , and Bradsher, C. K. Acc. chem. Res. 15,300 Parshall, G. W. J. Am. chem. Soc. , and Porri, L. 1. chem. Soc. Dalton Trans. 1961 Quinn, H.
Thus vinyl-, allyl- and many substituted methyl-lithium species are prepared from the corresponding tin, mercury, boron or silicon derivatives (Wakefield, 1974; Krief, 1980). 40), where ready removal of the insoluble tetraphenyltin facilitates product isolation. 41). 41 ) Such a reaction should be favoured if the stability of R-M' exceeds that of RM. In practice, most work has been done using organomercury derivatives, which have been shown to give organometallic compounds with a wide range of metals, including lithium, sodium, beryllium, magnesium, zinc, cadmium, aluminium, gallium, indium and tin.
40), where ready removal of the insoluble tetraphenyltin facilitates product isolation. 41). 41 ) Such a reaction should be favoured if the stability of R-M' exceeds that of RM. In practice, most work has been done using organomercury derivatives, which have been shown to give organometallic compounds with a wide range of metals, including lithium, sodium, beryllium, magnesium, zinc, cadmium, aluminium, gallium, indium and tin. 42). 43), X = halogen) is given, this method is mainly used for the preparation of organolithium compounds from organic halides which do not readily react with the metal.
An Introduction to Organometallic Chemistry by A.W. Parkins